A ruthenium complex as a single-component redox shuttle for electrochemical photovoltaics.

نویسندگان

  • Jeung Yoon Kim
  • Won Seok Yun
  • Ho-Jin Son
  • JaeDong Lee
  • Nak Cheon Jeong
چکیده

A primitive version of a ruthenium complex [Ru(bpy)3(2+)] was employed for the first time as a new conceptual "single-component redox shuttle" for dye-sensitized solar cells. This single shuttle led to a large enhancement of the open-circuit photovoltage (VOC) to ∼940 mV relative to that of conventional iodine-based shuttle and greatly increased the efficiency of the solar-to-electric energy conversion at lower illumination levels by a factor of ca. 5.6.

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عنوان ژورنال:
  • Chemical communications

دوره 51 36  شماره 

صفحات  -

تاریخ انتشار 2015